Solution (in my special case):
disabling "add certificate to browser" removed the warning only...
After investigating with procmon I found entries from "certimporter-1299.exe" wich was unable to find the Mozilla Firefox Profile's path... (This seemed to occure because the user's name contained a blank and a special german character (ä)). Moving the firefox profile to a path without problematic characters or blanks by editing the profiles.ini solved the problem entirely...
So, it wasn't the home edition...
THX for the advice "procmon"...
CYA all,
NHD